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塑料模具材料開裂分析及解決對策
1
基本數據
2
調查結果
2.1.可見一處開裂,開裂部附件的成型面可見因漏水而形成的褐色銹跡;
2.2.通過金相分析材料無異常,熱處理硬度在最高限度范圍內;
2.3.冷卻水孔的地方可見應力腐蝕開裂。
3
原因分析
3.1在成型豎立面可見橫裂紋,是以背后冷卻水孔A的應力腐蝕開裂部為起點,延伸到成型面;
3.2成型面的豎立面到背后冷卻水孔A的壁厚約4MM較薄,對模具的剛性差。
4
分析圖片
成型面?zhèn)龋☉Ωg開裂)
5
解決對策
5.1加厚冷卻水孔A部的壁厚,對于冷卻水孔直徑D的目標,能否將其壁厚改為1~1.5D左右;
5.2變更回火條件,對于耐應力腐蝕,中溫回火(350~400℃)比現在施行的高溫回火(500℃)更有利。
ABS注塑件怎么才能增加光亮度
在注塑生產中,塑件光澤不良的主要是:模具、注塑工藝、原料這三方面的原因。以下就此問題作如下簡述,歡迎指正評論!
一、注塑模具
1.模具型腔加工不良
如模具型腔有傷痕、微孔、磨損、粗糙等不足,勢必會反應到塑件上,使塑件光澤不良,對此,要精心加工模具,使型腔表面有較小的粗糙度,必要時可拋光鍍鉻。2.型腔表面污漬
如型腔表面有油污、水漬,或脫模劑使太多,會使塑件表面發(fā)暗、沒有光澤,對此,要及時清除油污和水漬,并限量使用脫模劑。
3.塑件脫模斜度太小
脫模斜度太小會造成脫模困難,或脫模時受力過大,使塑件表面光澤*佳,對此,要加大脫模斜度。
4.模具排氣不良
若排氣不良會造成過多氣體停留在模型內,也會導致光澤不良,對此,要檢查和修正模具排氣系統(tǒng)。
5.澆口或流道設計不當
澆口或流道截面積過小或突然變化,熔體在其中流動時受剪力作用太大,呈湍流動態(tài)流動,導致光澤不良,對此,應適當加大澆口和流道截面積。
二、注塑工藝
1.注射速度過小
注射速度過小造成塑件表面不密實,顯現光澤不良,對此,可適當提高注射速度。2.塑件冷卻不充分
如對于厚壁塑件冷卻不充分,其表面會發(fā)毛,光澤偏暗,對此,應改善冷卻系統(tǒng)。
3.保壓操作不當
如保壓壓力過小、保壓時間太短,使塑件密度不夠而光澤不良,對此,應增大保壓壓力和保壓時間。
4.若熔體溫度過低
當熔體流動過低時,使得流動性較差,易導致光澤不良,對此,應適當提高熔體溫度。
5.結晶樹脂冷卻不均勻
如PE、PP、POM等制作的塑件,如冷卻不均勻會導致光澤不良,對此,應改善冷卻系統(tǒng),使之均勻冷卻。
6.注射速度與澆口面積不匹配
如注塑速度過大,而澆口截面積又過小,則澆口附近會發(fā)暗而光澤不良,對此,可適當降低注射速度和增大澆口截面積。
三、原材料
1.原材料粒度差異較大
粒度差異較大使得難以均勻塑化,而光澤不良,對此,應將原材料進行篩分處理。
2.原料中二次料太多
如再生料或水口料加入太多,影響熔體的均勻塑化而光澤不良,對此,應減少再生料或水口料加入量。
3.原料耐溫性不良
有些原材料在調溫時會分解變色導致光澤不良,對此,應選用耐溫性較好的原材料。
4.原材料中含有易揮發(fā)物
如原料中水分或易揮發(fā)物含量過高,受熱時揮發(fā)成氣體,在型腔和熔體中凝縮,導致塑件光澤不良,對此,應對原材料進行預干燥處理。
5.添加劑的分散性不好
有些添加劑的分散性太差而使塑件光澤不良,對此,應改用流動性能較好的添加劑。
6.原材料不純
如原料中混有異物,雜料或不相溶的物料,它們不能與其原料均勻混熔在一起而導致光澤不良,對此,應事先嚴格排除這些雜料。
7.潤滑劑用量過少
如潤滑劑用量太少,熔體的流動性較差,塑件表面不致密,使得光澤不良,對此,應適當增加潤滑劑的用量。
所以,也要根據你的模具拋光度是否達到要求,如果模具本身沒有問題的話,要確定你的ABS的特性來確定,可以選擇高模溫,高速高壓;用冷凍水也能達到光潔度。
PA6 (polyamide # nylon 6)/S RCP3010LK/Italian lantiche
Purpose: other
Features note: good size stability, good rigidity, good surface finish, thermal stability, glass/mineral 30 % packing by weight
Important parameters: the density: 1.33 g/cm3 bibulous rate: 0.5% notched impact strength, tensile strength: 95 MPa elongation at break: 2.9% vicat softening point: 210 ℃ heat distortion temperature: 195 ℃
Manufacturer: rantich engineering plastics co. LTD
PA6 (polyamide # nylon 6)/S RCV3515 / Italian lantiche
Purpose: other
Features note: good size, low warp, good rigidity, good surface finish, glass bead/glass fiber 35% packing press weight
Important parameters: the density: 1.39 g/cm3 bibulous rate: 7.3% notched impact strength: 9.5 tensile strength: 125 MPa elongation at break: 3.2% vicat softening point: 210 ℃ heat distortion temperature: 190 ℃
Manufacturer: rantich engineering plastics co. LTD
PA6 (polyamide # nylon 6) / 1600 / carele billion
Purpose: automobile parts
Characteristic remarks: good dimensional stability, good rigidity, good impact resistance, good low temperature impact resistance, abrasion resistance and good weather resistance, oil resistance, 30% glass fiber reinforced material packing by weight
Important parameters: the density: 1.35 g/cm3 molding shrinkage rate: 0.2% notched impact strength: 220 tensile strength: 180 MPa elongation at break: 3% bending strength: 265 MPa bending modulus: 8450 MPa thermal deformation temperature: 200 ℃
Manufacturer: kelleyimei engineering plastics (Malaysia) co. LTD
PA6 (polyamide # nylon 6) / 6020HSL/lantiche USA
Purpose: other
Features note: glass fiber reinforced materials, 20% high gloss, the lubrication, dissolving resistance, machinability is good, good strength, high liquidity, good chemical resistance, fatigue resistance, oil resistance, good toughness, demoulding good performance
Important parameters: density: 1.3 g/cm3 absorption rate: 1.4 % molding shrinkage: 0.4 % notch impact strength: 91 fracture elongation: 4 % bending modulus: 6890 MPa hardness: 121
Manufacturer: rantich plastic American company
PA6 (polyamide # nylon 6)/SI00VI02BH14 / Spanish Triesa
Purpose: other
Feature remark: mineral packing 20% packing is good in weight, dimensional stability, good surface finish, thermal stability, stripping performance and good appearance
Important parameters: the density: 1.27 g/cm3 bibulous rate: 1% notched impact strength, tensile strength: 70 MPa elongation at break: 4% hardness: 79 vicat softening point: 220 ℃ heat distortion temperature: 140 ℃
Manufacturer: Triesa, Spain
PA6 (polyamide # nylon 6)/SI20CB01BH/Spain Triesa
Purpose: other
Characteristic remarks: carbon fiber reinforced material 20% packing press weight, high rigidity, good lubrication, good impact resistance, high heat resistance and thermal stability
Important parameters: the density: 1.22 g/cm3 bibulous rate: 1% notched impact strength, tensile strength: 175 MPa elongation at break: 3% hardness: 85 vicat softening point: 200 ℃ heat distortion temperature: 210 ℃
Manufacturer: Triesa, Spain
PA6 (polyamide # nylon 6)/PA - 211 / clariant chemical
Purpose: other
Features note: performance characteristics: good corrosion resistance, good dimensional stability, high rigidity, high strength, homopolymer, machinability is good, good color, good chemical resistance, good wear resistance, good toughness.
Important parameters: the density: 1.14 g/cm3 bibulous rate: 1.6% molding shrinkage rate: 1.2% notched impact strength, tensile strength: 53 79.3 MPa elongation at break: 75% bending strength: 110 MPa bending modulus: 2830 MPa hardness: 80 thermal deformation temperature: 73.9 ℃
Manufacturer: clariant chemical group
PA6 (polyamide # nylon 6)/B 280 G2 / Italian Taroplas
Purpose: other
Feature note: glass fiber increased by 10%. Performance characteristics: good anti-uv performance, thermal stability, good stripping performance.
Important parameters: the melt flow rate: 15 g / 10 min density: 1.16 g/cm3 bibulous rate: 1.5% molding shrinkage rate: 0.6% notched impact strength: 5 oxygen index: 24% tensile strength: 105 MPa elongation at break: 7% bending modulus: 4500 MPa hardness: 100 vicat softening point: 214 ℃ heat distortion temperature: 90 ℃
Manufacturer: Italian Taroplast thermoplastic engineering plastics co. LTD
PA6 (polyamide # nylon 6)/B 280 G4 X2 / Italian Taroplas
Purpose: other
Feature note: glass fiber increases by 20%. Characteristics: good fluidity, thermal stability, good mould performance, self-extinguishing.
Important parameters: the density: 1.26 g/cm3 bibulous rate: 1.6% molding shrinkage rate: 0.4% notched impact strength: oxygen index 4.4:30% tensile strength: 110 MPa elongation at break: 3.4% bending modulus: 6000 MPa vicat softening point: 204 ℃ heat distortion temperature: 180 ℃
Manufacturer: Italian Taroplast thermoplastic engineering plastics co. LTD
PA6 (polyamide # nylon 6)/B3 GF 30 9 RM - M black (3099)/German akro-plastic
USES: electronic electrical parts, automobile parts
Important parameters: the density: 1.41 g/cm3 molding shrinkage rate: 0.4% notched impact strength, tensile strength: 170 MPa bending strength: 250 MPa bending modulus: 9600 MPa hardness: 230 thermal deformation temperature: 205 ℃
Manufacturer: akro-plastic, Germany
PA6 (polyamide # nylon 6)/DP - 2-1851/30 * / lansheng (bayer)
Purpose: other
Features note: 30% glass fiber reinforced, UL94V - 0/0.75 mm (internal testing), and UL94V - 0/1.5 mm, GWFI: 960 ℃ / 1 mm, CTI/A: 450, GWIT: 775 ℃ / 0.75 mm
Important parameters: the density: 1.67 g/cm3 notched impact strength, tensile strength: 145 MPa elongation at break: 2% bending strength: 240 MPa bending modulus: 10600 MPa vicat softening point: 205 ℃ heat distortion temperature: 198 ℃ filler content: 30%
Manufacturer: lansheng chemistry, Germany
PA6 (polyamide # nylon 6)/pa6-r01 / changzhou hurley
USES: automobile parts, sports equipment
Feature remark: mineral filler is enhanced to improve the dimension precision, surface gloss of the shape of PA products, and the warp of the molding. (30% mineral enhancement)
Important parameters: the density: 1.35 g/cm3 molding shrinkage rate: 0.9% notched impact strength: 6.8 tensile strength: 90 MPa elongation at break: 3% bending strength: 145 MPa thermal deformation temperature: 165 ℃
Manufacturer: changzhou hurley plastic co. LTD
PA6 (polyamide # nylon 6)/dgk-tqw15 / new detech
USES: EMI, electronic components
Features: improved anti-impact, color, anti-static, conductive, carbon fiber reinforced flame retardant
Important parameters: the density: 1.22 g/cm3 molding shrinkage rate: 0.04% notched impact strength: 155 tensile strength: 154 MPa bending modulus: 4945 MPa thermal deformation temperature: 180 ℃
Manufacturer: yuyao xindegao plastic technology co. LTD
PA6 (polyamide # nylon 6) / 136F3Q32H/Austria SAX
Purpose: other
Features: improved impact resistance, high impact resistance, good processability, low temperature resistance and thermal stability
Important parameters: the density: 1.17 g/cm3 notched impact strength, tensile strength: 65 MPa elongation at break: 5% bending strength: 120 MPa bending modulus: 3300 MPa vicat softening point: 185 ℃ heat distortion temperature: 173 ℃
Manufacturer: Austria SAX polymer industrial co. LTD
PA6 (polyamide # nylon 6)/SW108 GRIS 7838/205263 / French AD majoris
USES: automotive parts, electronic components
Remarks: good surface finish, good compressive strength, glass bead increase 15%
Important parameters: the density: 1.25 g/cm3 bibulous rate: 2.5% molding shrinkage rate: 0.6% notched impact strength: 4.7 tensile strength: 80 MPa elongation at break: 30% bending strength: 138 MPa bending modulus: 3150 MPa thermal deformation temperature: 130 ℃
Manufacturer: AD majoris of France
PA6 (polyamide # nylon 6)/N602HSL_NAT/Italian lantich
Purpose: other
Characteristic remarks: lubricated, good melt strength, good flexibility, good chemical resistance, thermal stability, good toughness
Important parameters: the density: 1.08 g/cm3 bibulous rate: 1.9% notched impact strength, tensile strength of 210:41.4 MPa elongation at break: 100% bending strength, bending modulus of the 55.2 MPa, 758 MPa, thermal deformation temperature 45 ℃
Manufacturer: rantich engineering plastics co. LTD
PA6 (polyamide # nylon 6)/N603H/Italian lantiche
Purpose: other
Features: copolymer, anti-solubility, good processability, good chemical resistance, fatigue resistance, oil resistance, thermal stability, good toughness
Important parameters: the density: 1.1 g/cm3 bibulous rate: 1.5% molding shrinkage rate: 1.2% notched impact strength, tensile strength of 130:62.1 MPa elongation at break: 100% bending strength, bending modulus of the 82.7 MPa, 2070 MPa, thermal deformation temperature of 60 ℃
Manufacturer: rantich engineering plastics co. LTD
PA6 (polyamide # nylon 6)/N603HL/Italian lantiche
Purpose: other
Features: copolymer, lubrication, anti-solubility, good processability, good chemical resistance, fatigue resistance, oil resistance, thermal stability, good toughness
Important parameters: the density: 1.1 g/cm3 bibulous rate: 1.5% molding shrinkage rate: 1.2% notched impact strength, tensile strength of 130:62.1 MPa elongation at break: 100% bending strength, bending modulus of the 82.7 MPa, 2070 MPa, thermal deformation temperature of 60 ℃
Manufacturer: rantich engineering plastics co. LTD
PA6 (polyamide # nylon 6)/N60M40L/Italian lantiche
Purpose: other
Features: high rigidity, lubrication, anti - changing, good workability, good appearance, mineral packing 40% packing press weight
Important parameters: the density: 1.48 g/cm3 bibulous rate: 1% molding shrinkage rate: 0.8% notched impact strength: 37 tensile strength: 87 MPa elongation at break: 5% bending strength: 131 MPa bending modulus: 5520 MPa thermal deformation temperature: 116 ℃
Manufacturer: rantich engineering plastics co. LTD
PA6 (polyamide # nylon 6)/R 6 S GF 10 MV 20 / German Pal plast
Purpose: other
Properties note: glass fiber reinforced material 10% packing press weight, mineral packing 20% packing press weight, dimensional stability good, low warping, rigid good
Important parameters: the density: 1.35 g/cm3 bibulous rate: 1.7% notched impact strength, tensile strength: 110 MPa elongation at break: 3.5% vicat softening point: 207 ℃
Manufacturer: Pal plast, Germany